When we were using Bromine we were seeing similar problems. In our case the MPS would drive the Bromine very high for days and the Alk would go very low. I'm not sure the low alk was actually raising the ph or if the very high bromine was masking the ph reading. But, we always seemed to have high ph and low alk after shocking with MPS. I never really found a good way to keep the bromine from getting out of control and that was part of our decision to move to dichlor instead of bromine.